THERMAL REARRANGEMENT OF ALLYLIC CYANAMIDES

DOI: 10.1016/S0040-4039(00)85064-9

Source and publish data:

Tetrahedron Letters p. 4783 - 4786 (1986)

Update date:2022-08-04

Topics:

Authors:

Betancor, Carmen

Carrau, Reyes

Francisco, Cosme G.

Suarez, Ernesto

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Article abstract of DOI:10.1016/S0040-4039(00)85064-9

The allylic rearrangement of cyanamides has been achieved by pyrolysis in solution at temperatures between 125 and 190 deg C.This rearrangement was also observed during the thermal opening of the aziridine ring in cyanoaziridines.This allylic transportation constitutes a formal method for the 1,3-isomerization of allylic amines.

Full text of DOI:10.1016/S0040-4039(00)85064-9

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