THERMAL REARRANGEMENT OF ALLYLIC CYANAMIDES

DOI: 10.1016/S0040-4039(00)85064-9

Source and publish data:

Tetrahedron Letters p. 4783 - 4786 (1986)

Update date:2022-08-04

Topics:

Authors:

Betancor, Carmen

Carrau, Reyes

Francisco, Cosme G.

Suarez, Ernesto

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85064-9

The allylic rearrangement of cyanamides has been achieved by pyrolysis in solution at temperatures between 125 and 190 deg C.This rearrangement was also observed during the thermal opening of the aziridine ring in cyanoaziridines.This allylic transportation constitutes a formal method for the 1,3-isomerization of allylic amines.

Full text of DOI:10.1016/S0040-4039(00)85064-9

Products guided by the article

Product name:N-cinnamylcyanamide

Cas No:109058-91-5

R&D Labs maybe for 109058-91-5

qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct
Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town
Anhui Dexinjia Biopharm Co., Ltd

Contact:+86-531-82375818

Address:9 Hexie Road, kaifaqu, Taihe
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Zhejiang Hoshine Silicon Industry Co., Ltd.

Contact:86-573-89179966

Address:Zhapu Town, Pinghu City, Zhejiang, China

Relevant to this article

Design and synthesis of N-hydroxytriazole-4-carboxamides as HIV integrase inhibitors

Doi:10.1007/s00044-014-1136-4
(2015)
Unprecedented synthesis of a novel amino quinone ring system via oxidative decarboxylation of quinone-based α,α-amino esters

Doi:10.1039/b918898c
(2010)
Stereospecific synthesis of sec- and tert-alkyl azides from alcohols and trimethylsilyl azide by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite and trimethylsilylmethyl azide

Doi:10.1246/cl.2008.1072
(2008)
Synthesis of thiazole-4-carboxamide-adenine difluoromethylenediphosphonates substituted with fluorine at C-2' of the adenosine

Doi:10.1016/0008-6215(93)84063-C
(1993)
Synthesis, Conformation, and Structure of 8,11-Bis(methoxycarbonyl)<6>paracyclophane

Doi:10.1021/jo00389a002
(1987)
NOVEL SYNTHESES OF TRICYCLIC, N-ARYL, PYRIDINE- AND PYRAZINE-FUSED PYRIMIDONES

Doi:10.1135/cccc19931133
(1993)

Article Doi