A NEW PROCEDURE FOR HOMOLOGATION OF CARBONYL COMPOUNDS TO α-HYDROXY-CARBOXYLIC ESTERS BY MEANS OF DIETHYL-PHOSPHONATE

DOI: 10.1016/S0040-4039(00)85338-1

Source and publish data:

Tetrahedron Letters p. 5829 - 5832 (1986)

Update date:2022-08-05

Topics:

Authors:

Binder, Josef

Zbiral, Erich

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Article abstract of DOI:10.1016/S0040-4039(00)85338-1

A synthesis of α-hydroxyesters 5 using the Peterson olefination of the α-trimethylsilyl-substituted phosphonate 2 to vinylphosphonates 3 followed by hydroxylation with catalytical amounts of OsO4 has been developed.

Full text of DOI:10.1016/S0040-4039(00)85338-1

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