ENANTIOSELECTIVE SYNTHESIS OF 1-VINYL-1,2-DIOLS, VINYL EPOXIDES AND α,β-DIALKOXY ALDEHYDES

DOI: 10.1016/S0040-4039(00)80846-1

Source and publish data:

Tetrahedron Letters p. 5685 - 5688 (1988)

Update date:2022-08-02

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Authors:

Matsumoto, Takashi

Kitano, Yasunori

Sato, Fumie

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Article abstract of DOI:10.1016/S0040-4039(00)80846-1

A practical synthetic method of chiral γ-trimethylsilylmethyl allylic alcohols (1) with both E- and Z-configuration has been developed.The alcohols 1 are readily converted into 1-vinyl-1,2-diols (5) via diastereoselective epoxidation followed by the react

Full text of DOI:10.1016/S0040-4039(00)80846-1

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