3-Methyl-6-methylene-3-nitrocyclohexa-1,4-diene and (4-methyl-4- nitrocyclohexa-2,5-dienylidene)acetonitrile, intermediates in the rearomatizations of 1,4-dimethyl-4-nitrocyclohexa-2,5-dienyl acetate and (1-acetoxy-4-methyl-4-nitrocyclohexa-2,5-dienyl)acetonitrile

DOI: 10.1039/C39880000526

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 526 - 527 (1988)

Update date:2022-08-02

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Authors:

Fischer, Alfred

Goel, Alok

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Article abstract of DOI:10.1039/C39880000526

4-Methyl-4-nitro-1-trimethylsilylmethyl- (1e) and 4-methyl-4-nitro-1- cyanomethyl-cyclohexa-2,5-dienol (1c) in acidified acetic anhydride give 3-methyl-6-methylene-3-nitrocyclohexa-1,4-diene (3a) and (4-methyl-4- nitrocyclohexa-2,5-dienylidene)acetonitrile (3c), respectively.

Full text of DOI:10.1039/C39880000526

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