Synthesis of 4-Hetero-Substituted Pyranosides via Dioxenium Cation-Olefin Cyclization

DOI: 10.1021/jo00227a037

Source and publish data:

Journal of Organic Chemistry p. 4128 - 4130 (1987)

Update date:2022-08-04

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Authors:

Perron, Francoise

Albizati, Kim F.

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Article abstract of DOI:10.1021/jo00227a037

Ortho esters and homoallylic alcohols in the presence of Lewis acids stereoselectively provide 4-hetero-substituted pyranosides in the first examples of dioxenium cation onto unactivated olefins.

Full text of DOI:10.1021/jo00227a037

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