Lewis Acid Induced Nucleophilic Substitution Reactions of β-Nitro Sulfides via Episulfonium Ions

DOI: 10.1021/jo00227a039

Source and publish data:

Journal of Organic Chemistry p. 4133 - 4135 (1987)

Update date:2022-08-03

Topics:

Authors:

Ono, Noboru

Kamimura, Akio

Sasatani, Hiroyuki

Kaji, Aritsune

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00227a039

The nitro group of β-nitro sulfides is replaced by a cyano or allyl group via episulfonium intermediates on treatment with Me3SiY (Y=CN or allyl) in the presence of an appropriate Lewis acid.

Full text of DOI:10.1021/jo00227a039

Products guided by the article

Product name:2,2-dimethyl-3-(phenylthio)propionitrile

Cas No:109585-32-2

R&D Labs maybe for 109585-32-2

Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
Guangzhou PI & PI Biotech Inc. Ltd.

Contact:+86-20-81716320

Address:13th Floor, Xinbao Technology Industrial Park, No. 2 Ruixiang Road, Huangpu District, Guangzhou,Guangdong,China
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
Jiangsu Dacheng Pharmaceutical and Chemical Co.,Ltd

Contact:+86-0517-87036900

Address:Chuzhou Chemical park, Huai'an, Jiangsu Province
Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong

Relevant to this article

Catalytic Allylic Oxidation of Cyclic Enamides and 3,4-Dihydro-2H-Pyrans by TBHP

Doi:10.1021/acs.joc.7b01163
(2017)
Studies on sulfenamides. XII. Anodic oxidation of N-(o-nitrophenylthio)-1,2,3,4-tetrahydroquinoline and N-(o-nitrophenylthio)-1,2,3,4-tetrahydroisoquinoline

Doi:10.1248/cpb.34.4139
(1986)
An Efficient O-Monoalkylation of Dimethyl L-Tartrate via O-Stannylene Acetal with Alkyl Halides in the Presence of Cesium Fluoride

Doi:10.1246/cl.1987.141
(1987)
A new pentadentate ligand forms both a di- and a mononuclear Mn ^II complex: Electrochemical, spectroscopic and superoxide dismutase activity studies

Doi:10.1002/ejic.200601236
(2007)
Doi:10.1021/jo01090a017
(1959)
Synthesis and structure-activity relationship of berberine analogues in LDLR up-regulation and AMPK activation

Doi:10.1016/j.bmc.2012.09.029
(2012)

Article Doi