Lewis Acid Induced Nucleophilic Substitution Reactions of β-Nitro Sulfides via Episulfonium Ions

DOI: 10.1021/jo00227a039

Source and publish data:

Journal of Organic Chemistry p. 4133 - 4135 (1987)

Update date:2022-08-03

Topics:

Authors:

Ono, Noboru

Kamimura, Akio

Sasatani, Hiroyuki

Kaji, Aritsune

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Article abstract of DOI:10.1021/jo00227a039

The nitro group of β-nitro sulfides is replaced by a cyano or allyl group via episulfonium intermediates on treatment with Me3SiY (Y=CN or allyl) in the presence of an appropriate Lewis acid.

Full text of DOI:10.1021/jo00227a039

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