Studies in Biomimetic Alkaloid Syntheses. 16. Syntheses of D/E Trans and Cis Desethylvincadifformines and of the C16 Epimeric Carbomethoxydesethyldihydrocleavamines and Their Isolable Piperidine Ring Conformational Isomers

DOI: 10.1021/jo00228a034

Source and publish data:

Journal of Organic Chemistry p. 4331 - 4339 (1987)

Update date:2022-09-26

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Authors:

Kuehne, Martin E.

Zebovitz, Thomas C.

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Article abstract of DOI:10.1021/jo00228a034

Generation of D-secodesethylvincadifformine intermediate 18 allowed its conversion to D/E trans and D/E cis desethylvincadifformine (10 and 19) as well as to two C-16 epimeric carbomethoxydesethyldihydrocleavamines, each of the latter selectively obtained

Full text of DOI:10.1021/jo00228a034

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