FREE RADICAL ANNULATION OF CYCLOPENTANE RING

DOI: 10.1016/S0040-4039(00)85357-5

Source and publish data:

Tetrahedron Letters p. 5893 - 5896 (1986)

Update date:2022-07-30

Topics:

Authors:

Cekovic, Zivorad

Saicic, Radomir

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Article abstract of DOI:10.1016/S0040-4039(00)85357-5

Homoallyl radical, e.g. 2, reacts with an electron-deficient olefinic bond 1 with a new C-C bond forming and arising of a 5-hexenyl radical 3 which further undergoes to 5-exo-trigonal cyclization with a cyclopentane ring (4) annulation.

Full text of DOI:10.1016/S0040-4039(00)85357-5

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