A New Synthesis of Fused Heterocyclic and Carbocyclic Compounds via the Reaction of the Vinylphosphonate with Imide and Ketone Enolate Anions

DOI: 10.1246/cl.1986.2027

Source and publish data:

Chemistry Letters p. 2027 - 2030 (1986)

Update date:2022-08-05

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Authors:

Minami, Toru

Watanabe, Kazushi

Hirakawa, Kazunari

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Article abstract of DOI:10.1246/cl.1986.2027

The reaction of diethyl (α-ethoxycarbonylvinyl)phosphonate with various imide and ketone enolate anions gave functionalized heterocyclic and carbocyclic, and spirocarbocyclic compounds containing the phosphorus residue in good yields.

Full text of DOI:10.1246/cl.1986.2027

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Product name:Spiro[4.5]dec-6-ene-7,9-dicarboxylic acid, 9-(diethoxyphosphinyl)-1-oxo-6-phenyl-, diethyl ester

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