Journal of the American Chemical Society p. 5013 - 5019 (1987)
Update date:2022-07-30
Topics:
Guilford, William J.
Copley, Shelley D.
Knowles, Jeremy R.
To probe the mechanistic pathway of the reaction catalyzed by chorismate mutase, the secondary tritium isotope effect at C-4 of chorismate, kH/kT, has been determined.The small inverse effect of 0.96 rules out pathways that involve g
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