A New Synthesis of 3-Hydroxy-2,5-dialkyl-1,4-benzoquinones Using Iodine-Copper(II) Acetate

DOI: 10.1246/cl.1987.393

Source and publish data:

Chemistry Letters p. 393 - 396 (1987)

Update date:2022-08-05

Topics: Synthesis Organic synthesis Alkyl Hydroxyl Benzoquinone

Authors:

Horiuchi, C. Akira

Suzuki, Yasuto

Takahashi, Masaaki

Satoh, J. Yasuo

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Article abstract of DOI:10.1246/cl.1987.393

Reactions of diosphenol and 3,6-dimethyl-1,2-cyclohexanedione with iodine-copper(II) acetate in acetic acid-water (5:1) at 80 deg C gave the respective 3-hydroxy-2,5-dialkyl-1,4-benzoquinone in 25-80 percent yields. 2-t-Butyl-5-methylcyclohexanone similar

Full text of DOI:10.1246/cl.1987.393

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