CARBONYL ADDITION REACTION BY MEANS OF β-SILYLPHOSPHOROUS YLIDE. ANTI-DIASTEREOSELECTIVE VINYLATION OF α-ALKOXY ALDEHYDES.

DOI: 10.1016/S0040-4039(00)87812-0

Source and publish data:

Tetrahedron Letters p. 6373 - 6376 (1986)

Update date:2022-08-04

Topics: Vinylation

Authors:

Iio, Hideo

Mizobuchi, Tsukasa

Tsukamoto, Masamitsu

Tokoroyama, Takashi

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β-Silylphosphorous ylide 1c reacts with α-alkoxy aldehydes 2 to give exclusively vinylation product 3, with high anti-diastereoselectivity.

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