614 J. Agric. Food Chem., Vol. 57, No. 2, 2009
Table 3. 1H NMR Data of Compounds 3
compound no.
Meng et al.
1H NMR, δ
3A1-1(1)
3A1-1(2)
3A1-2(1)
3A1-2(2)
3A1-3(1)
3A1-3(2)
3A1-4(1)
3A1-4(2)
3A1-5(1)
3A1-5(2)
3A1-6(1)
3A1-6(2)
3A1-7(1)
3A1-7(2)
3A1-8(1)
3A1-8(2)
3A1-9(1)
3A1-9(2)
3A1-10(1)
3A1-10(2)
3A1-11(1)
3A1-11(2)
3A1-12(1)
3A1-12(2)
3A1-13(1)
3A1-13(2)
1.36∼1.40(m, 12H), 1.54∼1.67(m, 4H), 1.75∼1.84(m, 2H), 2.30∼2.35(m, 4H), 2.41∼2.47(m, 2H), 4.04(t, 2H, J ) 5.8 Hz), 4.93(s, 2H),
6.96∼7.00(m, 3H), 7.28∼7.35(m, 2H)
1.27∼1.34(m, 12H), 1.34∼1.56(m, 2H), 1.62∼1.67(m, 2H), 1.90∼1.99(m, 2H), 2.30∼2.41(m, 4H), 2.45∼2.50(m, 2H), 4.16∼4.20(m, 2H), 4.94(s,
2H), 6.95∼7.00(m, 3H), 7.28∼7.33(m, 2H)
1.36∼1.44(m, 12H), 1.56∼1.67(m, 4H), 1.75∼1.83(m, 2H), 2.26(s, 3H), 2.30∼2.35(m, 4H), 2.41∼2.46(m, 2H), 4.03(t, 2H, J ) 5.8 Hz), 4.95(s,
2H), 6.85∼6.90(m, 2H), 7.12∼7.19(m, 2H)
1.26∼1.33(m, 12H), 1.45∼1.55(m, 2H), 1.60∼1.69(m, 2H), 1.90∼1.99(m, 2H), 2.25(s, 3H), 2.30∼2.40(m, 4H), 2.45∼2.50(m, 2H), 4.16∼4.20(m,
2H), 4.96(s, 2H), 6.85∼6.89(m, 2H), 7.11∼7.18(m, 2H)
1.36∼1.40(m, 12H), 1.54∼1.67(m, 4H), 1.74∼1.83(m, 2H), 2.26(s, 3H), 2.30∼2.35(m, 4H), 2.40∼2.46(m, 2H), 4.03(t, 2H, J ) 5.8 Hz), 4.88(s,
2H), 6.86(dd, 2H, J ) 6.6 Hz, J ) 2.1 Hz), 7.11(dd, 2H, J ) 8.8 Hz, J ) 0.7 Hz)
1.26∼1.33(m, 12H), 1.45∼1.55(m, 2H), 1.60∼1.69(m, 2H), 1.90∼1.96(m, 2H), 2.25(s, 3H), 2.30∼2.40(m, 4H), 2.44∼2.50(m, 2H), 4.16∼4.20(m,
2H), 4.89(s, 2H), 6.83-6.88(m, 2H), 7.08∼7.12(m, 2H)
1.36∼1.39(m, 12H), 1.56∼1.67(m, 4H), 1.78∼1.83(m, 2H), 2.30∼2.35(m, 4H), 2.41∼2.48(m, 2H), 3.74(s, 3H), 4.05(t, 2H, J ) 5.8 Hz), 4.86(s,
2H), 6.85∼6.94(m, 4H)
1.29∼1.34(m,12H), 1.49∼1.54(t, 2H), 1.62∼1.67(m, 2H), 1.92∼1.96(m, 2H), 2.30∼2.41(m, 4H), 2.45∼2.50(m, 2H), 3.74(s, 3H),4.18(t,2H, J ) 5.6
Hz),4.86(s, 2H), 6.84∼6.93(m, 4H)
1.30∼1.45(m, 12H), 1.54∼1.67(m, 4H), 1.77∼1.86(m, 2H), 2.30∼2.36(m, 4H), 2.43∼2.49(m, 2H), 4.06(t, 2H, J ) 5.8 Hz), 5.06(s, 1H),
6.97∼7.03(m, 1H), 7.09-7.12(m,1H), 7.27-7.33(m, 1H), 7.42-7.45(m, 1H)
1.25∼1.35(m, 12H), 1.48∼1.53(m, 2H), 1.62∼1.67(m, 2H), 1.90∼1.99 (m, 2H), 2.30∼2.41(m, 4H), 2.45∼2.50(m, 2H), 4.16∼4.20(m, 2H), 5.07(s,
2H), 6.97∼7.02(m, 1H), 7.08∼7.12(m, 1H), 7.26∼7.31(m, 1H), 7.41∼7.44(m, 1H)
1.36∼1.44(m, 12H), 1.57∼1.67(m, 4H), 1.80∼1.86(m, 2H), 2.30∼2.36(m, 4H), 2.44∼2.50(m, 2H), 4.08(t, 2H, J ) 5.8 Hz), 5.00(s, 2H),
6.94∼7.05(m, 3H), 7.30∼7.36(m, 1H)
1.28∼1.34(m, 12H), 1.50∼1.54(m, 2H), 1.63∼1.67(m, 2H), 1.92∼1.99(m, 2H), 2.31∼2.82(m, 6H), 4.18(t, 2H, J ) 5.6 Hz), 5.02(s, 2H),
6.94∼7.05(m, 3H), 7.30∼7.36(m, 1H)
1.35∼1.50(m, 12H), 1.54∼1.67(m, 4H), 1.18∼1.87(m, 2H), 2.30∼2.36(m, 4H), 2.44∼2.49(m, 2H), 4.07(t, 2H, J ) 5.8 Hz), 4.97(s, 2H),
6.98∼7.04(m, 2H), 7.30∼7.36(m, 2H)
1.25∼1.35(m, 12H), 1.48∼1.53(m, 2H), 1.64∼1.67(m, 2H), 1.90∼1.99(m, 2H), 2.30∼2.41(m, 4H), 2.45∼2.50(m, 2H), 4.18(t, H, J ) 5.6 Hz),
4.98(s, 2H), 6.99∼7.03(m, 2H), 7.29∼7.34(m, 2H)
1.36∼1.41(m, 12H), 1.57∼1.67(m, 4H), 1.83∼1.87(m,2 H), 2.30∼2.37(m, 4H), 2.47∼2.52(m, 2H), 4.09(t, 2H, J ) 5.8 Hz), 5.16(s, 2H),
7.45∼7.49(m, 1H), 7.60∼7.65(m, 1H), 7.79-7.81(m, 1H), 7.87∼7.91(m, 1H)
1.30-1.34(m, 12H), 1.50-1.55(m, 2H), 1.62∼1.67(m, 2H), 1.92∼1.97(m, 2H), 2.30∼2.35(m, 2H), 2.39∼2.51(m, 4H), 4.18(t, 2H, J ) 5.6 Hz),
5.19(s, 2H), 7.44∼7.48(m, 1H), 7.62-7.65(m, 1H), 7.79-7.81(m, 1H), 7.87∼7.91(m, 1H)
1.36∼1.44(m, 12H), 1.53∼1.66(m, 4H), 1.72∼1.79(m, 2H), 2.19(s, 3H), 2.26(s, 3H), 2.30∼2.35(m, 4H), 2.39∼2.45(m, 2H), 4.01(t, 2H, J ) 5.7
Hz), 4.92(s, 2H), 6.72∼6.81(m, 2H), 7.00-7.05(m, 1H)
1.26∼1.33(m, 12H), 1.47∼1.52(m, 2H), 1.62∼1.67(m, 2H), 1.91∼1.98(m, 2H), 2.18(s, 3H), 2.25(s, 3H), 2.30∼2.40(m, 4H), 2.44∼2.49(m, 2H),
4.16∼4.20(m, 2H), 4.92(s, 2H), 6.72∼6.80(m, 2H), 7.00-7.05(m, 1H)
1.26∼1.40(m, 12H), 1.59∼1.65(m, 4H), 1.78∼1.88(m, 2H), 2.17(s, 3H), 2.22(s, 3H), 2.28∼2.34(m, 4H), 2.38∼2.44(m, 2H), 4.00(t, 2H, J ) 5.8
Hz), 4.86(s, 2H), 6.66-6.0(m, 1H), 6.77-6.79(m, 1H), 7.02-7.05(m, 1H)
1.25∼1.33(m, 12H), 1.45∼1.54(m, 2H), 1.62∼1.67(m, 2H), 1.89∼1.98(m, 2H), 2.16(s, 3H), 2.21(s, 3H), 2.30∼2.40 (m, 4H), 2.44∼2.49(m, 2H),
4.18(t, 2H, J ) 5.6 Hz), 4.87(s, 2H), 6.66∼6.69(m, 1H), 6.77∼6.78(m, 1H), 7.02∼7.04(m, 1H)
1.36∼1.44(m, 12H), 1.55∼1.67(m, 4H), 1.77∼1.87(m, 2H), 2.26 (s, 3H), 2.30∼2.36(m, 4H), 2.44∼2.49(m, 2H), 4.07(t, 2H, J ) 5.8 Hz), 4.99(s,
2H), 6.92(d, 1H, J ) 8.7 Hz), 7.15∼7.22 (m, 2H)
1.26∼1.33(m, 12H), 1.47∼1.52(m, 2H), 1.62∼1.66(m, 2H), 1.91∼1.98(m, 2H), 2.25(s, 3H), 2.30∼2.40(m, 4H), 2.45∼2.50(m, 2H), 4.18(t, 2H, J )
5.6 Hz), 4.99(s, 2H), 6.91(d, 1H, J ) 8.7 Hz), 7.13-7.21(m, 2H)
1.25-1.44(m, 14H), 1.57-1.97(m, 6H), 2.28-2.47(m, 4H), 4.07(t, 2H, J)5.6 Hz), 4.87(s, 2H), 6.80-6.87(m, 1H), 7.15-7.21(m, 1H),
7.37-7.42(m, 1H)
1.27-1.44(m, 14H), 1.63-1.97(m, 6H), 2.31-2.37(m, 2H), 2.42-2.47(m, 2H), 4.18(t, 2H, J)5.6 Hz), 4.87(s, 2H), 6.81-6.85(m, 1H),
7.16-7.20(m, 1H), 7.37-7.40(m, 1H)
1.36∼1.44(m,12H), 1.57∼1.67(m, 4H), 1.81∼1.88(m, 2H), 2.31∼2.36(m, 4H), 2.45∼2.51(m, 2H), 4.09(t, 2H, J ) 5.8 Hz), 5.10(s, 2H), 7.10(d, 1H,
J ) 8.9 Hz), 7.47(dd, 1H, J)8.9 Hz, J ) 2.4 Hz), 7.62(d, 1H, J ) 2.4 Hz)
1.27∼1.34(m, 12H), 1.45∼1.55(m, 2H), 1.62∼1.67(m, 2H), 1.90∼1.99(m, 2H), 2.30∼2.41(m, 4H), 2.45∼2.50(m, 2H), 4.18(t, 2H, J ) 5.6 Hz),
5.11(s, 2H), 7.10(d, 1H, J ) 8.9 Hz), 7.45(dd, 1H, J ) 8.9 Hz, J ) 2.4 Hz), 7.61(d, 1H, J ) 2.4 Hz)
3A2-1(1)
3A2-1(2)
1.35(s, 12H),1.51∼1.77(m, 9H),2.28∼2.39(m, 6H), 3.99(t, 2H, J ) 5.6 Hz), 5.06(q, 1H, J ) 6.7 Hz), 6.94∼7.00(m, 3H, 7.27∼7.33(m, 2H))
1.22∼1.46(m, 14H), 1.62∼1.66(m, 5H), 1.89∼1.94 (m, 2H), 2.28∼2.35(m, 4H), 2.42∼2.47(m, 2H), 4.16(t, 2H, J ) 5.6 Hz), 5.06(q, 1H, J ) 6.8
Hz), 6.92∼6.99(m, 3H), 7.27∼7.32(m, 2H)
3A2-2(1)
3A2-2(2)
3A2-3(1)
3A2-3(2)
3A2-4(1)
3A2-4(2)
3A2-5(1)
3A2-5(2)
3A2-6(1)
1.26-1.90(m, 12H), 1.53∼1.76(m, 9H), 2.25∼2.38(m, 9H), 3.98 (t, 2H, J ) 5.7 Hz), 5.00(q, 1H, J ) 6.7 Hz), 6.83∼6.85(m, 2H), 7.09∼7.12(m,
2H)
1.21∼1.46(m, 14H), 1.60∼1.66(m, 5H), 1.89∼1.94(m, 2H), 2.24∼2.35(m, 7H), 2.42∼2.47(m, 2H), 4.14∼4.18(m, 2H), 4.99(q, 1H, J ) 6.7 Hz),
6.80∼6.84(m, 2H), 7.06∼7.11(m, 2H)
1.35∼1.39(m, 12H), 1.53∼1.80(m, 9H), 2.28∼2.44(m, 6H), 3.99∼4.03(m, 2H), 5.17(q, 1H, J ) 6.7 Hz), 6.97∼7.08(m, 2H), 7.26∼7.32(m, 1H),
7.43∼7.46(m, 1H)
1.22∼1.47(m, 14H), 1.61∼1.71(m, 5H), 1.87∼1.95(m, 2H), 2.25∼2.38(m, 4H), 2.44∼2.47(m, 2H), 4.16(t, 2H, J ) 5.6 Hz), 5.17(q, 1H, J ) 6.8
Hz), 6.96∼7.07(m, 2H), 7.25∼7.30(m, 1H), 7.41∼7.45(m, 1H)
1.35∼1.39(m, 12H), 1.54∼1.81(m, 9H), 2.29∼2.44(m, 6H), 4.03(t, 3H, J ) 5.6 Hz), 5.16(q, 1H, J ) 6.7 Hz), 6.91∼6.95 (m, 1H), 7.01∼7.04(m,
2H), 7.30∼7.36(m, 1H)
1.23∼1.32(m, 12H), 1.40∼1.49(m, 2H), 1.55-1.72(m, 5H), 1.87∼1.96(m, 2H), 2.27∼2.39(m, 4H), 2.43∼2.48 (m, 2H), 4.16(t, 2H, J ) 5.6 Hz),
5.15(t, 1H, J ) 6.8 Hz), 6.90∼6.94(m, 1H), 6.99∼7.03(m, 2H), 7.29∼7.34(m, 1H)
1.35∼1.39(m, 12H), 1.54∼1.80(m, 9H), 2.29∼2.43(m, 6H), 4.03(t, 2H, J ) 5.7 Hz), 5.09(q, 1H, J ) 6.8 Hz), 6.96∼7.01(m, 2H), 7.30∼7.35(m,
2H)
1.21∼1.47(m, 14H), 1.60-1.65(m, 5H), 1.86-1.96(m, 2H), 2.23∼2.48(m, 6H), 4.16(t, 2H, J ) 5.6 Hz), 5.09(q, 1H, J ) 6.7 Hz), 6.95∼7.00 (m,
2H), 7.29∼7.34(m, 2H)
1.34∼1.38(m, 12H), 1.50∼1.72(m, 9H), 2.18(s, 3H), 2.23∼2.36(m, 9H), 3.91∼3.96(m, 2H), 4.97∼5.04(m, 1H), 6.70(d, 1H, J ) 8.2 Hz), 6.79(d,
1H, J ) 7.6 Hz), 6.98-7.03(m, 1H)