Thermal and Photochemical Electron-Transfer Reactions of 4-Chlorobiphenyl with Lithium Diisopropylamides and Diisopropylamine

DOI: 10.1246/bcsj.60.788

Source and publish data:

Bulletin of the Chemical Society of Japan p. 788 - 790 (1987)

Update date:2022-08-02

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Authors:

Tanaka, Yoshio

Tsujimoto, Kazuo

Ohashi, Mamoru

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Article abstract of DOI:10.1246/bcsj.60.788

A reaction of 4-chlorobiphenyl with lithium diisopropylamide in a polar solvent gave 3- and 4-(diisopropylamino)biphenyl together with biphenyl, similar to the case of photoinduced reactions of 4-chlorobiphenyl with diisopropylamine.A common electron-transfer mechanism is proposed.

Full text of DOI:10.1246/bcsj.60.788

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