RADICAL CYCLIZATION TO FLUORINATED DOUBLE BONDS: 5-EXO RING CLOSURE OF BROMOACETALS DERIVED FROM FLUOROALLYL ALCOHOLS

DOI: 10.1016/S0040-4039(00)95809-X

Source and publish data:

Tetrahedron Letters p. 671 - 674 (1987)

Update date:2022-07-29

Topics: Product Isolation and Purification Termination and Isolation

Authors:

Morikawa, Tsutomu

Nishiwaki, Tohru

Iitaka, Yoichi

Kobayashi, Yoshiro

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Article abstract of DOI:10.1016/S0040-4039(00)95809-X

A radical<1> cyclized to the fluorinated double bond in selective 5-exo mode to afford tetrahydrofuran derivates<6>, and subsequent oxidation provided means for the syntheses of fluorinated γ-butyrolactones<8> and butenolide<9>.

Full text of DOI:10.1016/S0040-4039(00)95809-X

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