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Reaction of Terminal Oxiranes With Arenesulfonic Acid

DOI: 10.1055/s-1987-27918

Source and publish data:

Synthesis p. 281 - 284 (1987)

Update date:2022-07-29

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Authors:

Ogawa, KazuoOgawa, Kazuo

Ohta, ShunsakuOhta, Shunsaku

Okamoto, MasaoOkamoto, Masao

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Article abstract of DOI:10.1055/s-1987-27918

The reaction of oxiranes 1 with arenesulfonic acids under phase transfer catalyst system (water/dichloromethane) or without catalyst (dry dichloromethane) affords regioisomeric arylsulfonyloxy primary and secondary alcohols.The latter is oxidized to 1-arylsulfonyloxy-2-alkanones 5 in good yield.

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Full text of DOI:10.1055/s-1987-27918

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