Regioselective Alkylation of 3-(Trimethylsilyl)-3-sulfolene: Route to Stereospecific 2-Silylated Butadiene Derivatives

DOI: 10.1021/jo00236a014

Source and publish data:

Journal of Organic Chemistry p. 69 - 72 (1988)

Update date:2022-08-04

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Authors:

Tao, Yu-Tai

Chen, Man-Li

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Article abstract of DOI:10.1021/jo00236a014

Dichotomous regiochemistry in the alkylation of 3-(trimethylsilyl)-3-sulfolene (1) can be achieved by controlling the amount of base used (to generate the monoanion or the dianion) and the sequence of its addition.In this way, a variety of 2-silyl-1,3-but

Full text of DOI:10.1021/jo00236a014

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