Tetrahedron p. 3215 - 3222 (1986)
Update date:2022-08-04
Topics:
Magnus, Philip
Pappalardo, Paul
Southwell, Ian
Treatment of 4 with MCPBA gave 9.The pentacyclic amide 3 on exposure to cyanogen chloride gave the cis-chloro-hydrin 20, and the geminal dichloride 21.When 21 was treated with HCl/MeOH it rapidly rearranged to eburnamonine lactam 22.
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