Journal of the Chemical Society. Chemical communications p. 644 - 645 (1987)
Update date:2022-09-26
Topics:
Cervello, Jordi
Marquet, Jorge
Moreno-Manas, Marcial
The cobalt(II) complex of the simple polyketide model methyl 3,5-dioxohexanoate is regioselectively alkylated to afford methyl 4-alkyl-3,5-dioxohexanoates, which cyclize on treatment with 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) to give 5-alkyl-4-hydroxy-
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