Reactions of methylene active compounds with peroxorhodium phosphino complexes. Formation of hydroperoxorhodium complexes

DOI: 10.1016/0022-328X(87)85101-X

Source and publish data:

Journal of Organometallic Chemistry p. 337 - 344 (1987)

Update date:2022-09-26

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Authors:

Morvillo, Antonino

Bressan, Mario

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Article abstract of DOI:10.1016/0022-328X(87)85101-X

Reactions of active methylene compounds HA (malononitrile, β-diketones, cyclopentadiene) with the dioxygen adduct BF4 give new hydroperoxorhodium(III) complexes of the type A)OOH>BF4.The complexes readily convert PPh3 into OPPh3, but do not oxidise ketones or olefins, which instead undergo extensive isomerization.

Full text of DOI:10.1016/0022-328X(87)85101-X

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