SYNTHESE REGIOSPECIFIQUE D'ALLENES TERMINAUX A PARTIR DE PROPARGYLTRIMETHYLSILANES SIMPLES OU FONCTIONNELS

DOI: 10.1016/S0022-328X(00)99606-2

Source and publish data:

Journal of Organometallic Chemistry p. 333 - 344 (1987)

Update date:2022-08-02

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Authors:

Pornet, J.

Damour, D.

Miginiac, L.

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Article abstract of DOI:10.1016/S0022-328X(00)99606-2

Protodesilylation of varied propargyltrimethylsilanes, using boron trifluoride-acetic acid as reagent, give regiospecifically terminal allenes with very good yields.Yet, particular ω-functional propargyltrimethylsilanes may lead to vinylsilanes resulting

Full text of DOI:10.1016/S0022-328X(00)99606-2

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