A new enantiodivergent procedure utilising the chemoselective Dieckmann-type cyclisation of chiral mono-thiol diesters

DOI: 10.1039/cc9960001775

Source and publish data:

Chemical Communications p. 1775 - 1776 (1996)

Update date:2022-07-29

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Authors:

Sano, Shigeki

Ushirogochi, Hideki

Morimoto, Kenji

Tamai, Satoshi

Nagao, Yoshimitsu

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Article abstract of DOI:10.1039/cc9960001775

The chiral mono-thiol diester, 1 or 2, is converted to the corresponding enantiomeric cyclised products, (-)-7 and (+)-7 or (-)-9 and (+)-9, depending on whether LDA or A1Cl₃-Et₃N is used.

Full text of DOI:10.1039/cc9960001775

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