A new enantiodivergent procedure utilising the chemoselective Dieckmann-type cyclisation of chiral mono-thiol diesters

DOI: 10.1039/cc9960001775

Source and publish data:

Chemical Communications p. 1775 - 1776 (1996)

Update date:2022-07-29

Topics:

Authors:

Sano, Shigeki

Ushirogochi, Hideki

Morimoto, Kenji

Tamai, Satoshi

Nagao, Yoshimitsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/cc9960001775

The chiral mono-thiol diester, 1 or 2, is converted to the corresponding enantiomeric cyclised products, (-)-7 and (+)-7 or (-)-9 and (+)-9, depending on whether LDA or A1Cl₃-Et₃N is used.

Full text of DOI:10.1039/cc9960001775

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:((1R,6S)-6-Phenylsulfanylcarbonylmethyl-cyclohex-3-enyl)-acetic acid methyl ester

Cas No:112168-16-8

R&D Labs maybe for 112168-16-8

China Synchem Technology Co.,Ltd

website:http://www.cnsynchem.com

Contact:+86-0552-4929311

Address:No.217 Daqing Road
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Borun Chemical Co.,Ltd.

Contact:+86-574- 87178138; 87297407

Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China

Relevant to this article

Regioselective Opening of Simple Epoxides with Diisopropylamine Trihydrofluoride

Doi:10.1021/jo00240a017
(1988)
Thiophene as a structural element of physiologically active compounds. 16. Thienoisoxazoles by substitution at the oxime nitrogen

Doi:10.1002/ardp.19873200911
(1987)
Doi:10.1021/jo01357a025
(1957)
Chiral Synthesis via Organoboranes. 13. A Highly Diastereoselective and Enantioselective Addition of <(Z)-γ-Alkoxyallyl>diisopinocampheylboranes to Aldehydes

Doi:10.1021/ja00213a029
(1988)
Highly efficient and reversible iodine capture using a metalloporphyrin- based conjugated microporous polymer

Doi:10.1039/c4cc01783h
(2014)
An electron-deficient diene as ligand for palladium-catalyzed cross-coupling reactions: An efficient alkylation of aryl iodides by primary and secondary alkylzinc reagents

Doi:10.1002/adsc.200800118
(2008)

Article Doi