Journal of Organic Chemistry p. 1026 - 1030 (1988)
Update date:2022-07-29
Topics:
Muehlbacher, Manfred
Poulter, C. Dale
Treatment of benzyl ether derivatives of simple aliphatic epoxy alcohols with diisopropylamine trihydrofluoride gave mixtures of the corresponding fluorohydrins in good yields.Steric hindrance is a major factor in determining the regioselectivity of epoxide opening, although electronic effects cannot be ignored.Electronic effects are more dominant with pyridine polyhydrofluoride.
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