Journal of Organic Chemistry p. 845 - 850 (1988)
Update date:2022-08-04
Topics: Substituted Experimental Regioselective synthesis Pyranosides
Dunkerton, Lois V.
Adair, Nancy K.
Euske, Jack M.
Brady, Kevin T.
Robinson Paul D.
A variety of 1-thiohex-2-enopyranosides have been prepared from their corresponding 3-O-methyl- or 3-O-acetylglycals by using trimethylsilyl thiols catalyzed by BF3 etherate.This method is regioselective for thiolation at C-1 in contrast to the same react
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