INTER- AND INTRAMOLECULAR EPOXIDATION UTILIZING SILYL-PROTECTED PEROXY ESTERS AND COPPER SALT

DOI: 10.1016/S0040-4039(00)96007-6

Source and publish data:

Tetrahedron Letters p. 1909 - 1912 (1987)

Update date:2022-07-30

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Authors:

Saito, Isao

Mano, Takashi

Nagata, Ryu

Matsuura, Teruo

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Article abstract of DOI:10.1016/S0040-4039(00)96007-6

A new epoxidation method utilizing α-siloxyalkyl peroxybenzoate and Cu(OCOCF3)2 is described.Regioselective epoxidation of all trans farnesol is accomplished by the intramolecular version of this method.

Full text of DOI:10.1016/S0040-4039(00)96007-6

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Product name:Benzenecarboperoxoic acid, 2-[[(3,7,11-trimethyl-2,6,10-dodecatrienyl)oxy]carbonyl]-, 1-cyclopropyl-1-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl ester, (E,E)-

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