Distance and Orientation Dependence of Electron Transfer and Exciplex Formation of Naphthyl and p-Dimethylanilino Groups Fixed on a Helical Polypeptide Chain

Article abstract of DOI:10.1021/j100379a017

Polypeptides carrying a p-(dimethylamino)phenyl group (D) and a naphthyl group (N) at the middle of an α-helix chain were synthesized.The separation between D and N groups was varied by inserting different numbers (m) of alanyl units between them.The inte