Alkyl, aryl and cis-dihydride complexes of iridium with the tripodal phosphine P(CH2CH2PPh2)3 as excellent precursors of active systems for the activation of hydrocarbon C-H bonds

DOI: 10.1016/0022-328X(87)80170-5

Source and publish data:

Journal of Organometallic Chemistry p. C79 - C82 (1987)

Update date:2022-08-04

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Authors:

Bianchini, Claudio

Peruzzini, Maurizio

Zanobini, Fabrizio

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Article abstract of DOI:10.1016/0022-328X(87)80170-5

The C-H bonds of tetrahydrofuran, acetone and benzene are activated by the fragment <(PP3)Ir>(1+) (PP3 = P(CH2CH2PPh2)3) generated either by photolytic dehydrogenation of the cis-dihydride <(PP3)IrH2>(SO3CF3) or by thermal decomposition of the cis-(organy

Full text of DOI:10.1016/0022-328X(87)80170-5

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Product name:chloro[tris(2-(diphenylphosphino)ethyl)phosphine]iridium

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