Synthesis of (±)-nitramine and (±)-isonitramine by utilizing stereoselective reduction of ethyl 1-(3-bromopropyl)-2-oxocyclohexanecarboxylate

DOI: 10.3987/com-97-s40

Source and publish data:

Heterocycles p. 413 - 420 (1997)

Update date:2022-09-26

Topics:

Authors:

Senboku, Hisanori

Hatazawa, Mamoru

Orito, Kazuhiko

Tokuda, Masao

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Article abstract of DOI:10.3987/com-97-s40

Formal synthesis of (±)-nitramine (1) and (±)-isonitramine (2) was achieved. Thus, the reduction of ethyl 1-(3-bromopropyl)-2-oxocyclohexanccarboxylate (6) with NaBH₄ in MeOH gave the corresponding cyclohexanol (7) having cis geometry between h

Full text of DOI:10.3987/com-97-s40

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