Journal of Organic Chemistry p. 1475 - 1481 (1988)
Update date:2022-07-30
Topics:
Kornblum, Nathan
Ackermann, Peter
Manthey, Joseph W.
Musser, Michael T.
Pinnick, Harold W.
et al.
A number of groups that do not participate in SN2 displacement processes are able to function as leaving groups in electron-transfer chain reactions at room temperature; such groups include azide, sulfone, ethers, nitro, quaternary ammonium ions, esters, and thioethers.Even carbanions are able to function as leaving groups as can be seen from fragmentation of carbon-carbon bonds.
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Doi:10.1021/ic801589q
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