Tetrahedron Letters p. 3619 - 3622 (1987)
Update date:2022-08-03
Topics:
Whitby, Richard
Kocienski, Philip
Base-catalysed rearrangement of a 2-alkynyl-tetrahydropyran generates an allenol ether intermediate which undergoes acid-catalysed cyclisation to the 1,6-dioxaspiro<4.5>dec-3-ene system.
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