Journal of the Chemical Society. Perkin transactions II p. 1039 - 1042 (1987)
Update date:2022-08-05
Topics:
Armesto, Diego
Horspool, William M.
Langa, Fernando
Perez-Ossorio, Rafael
The u.v. irradiation of several 1-aryl derivatives of 3,3-dimethyl-5,5-diphenyl-1-azapenta-1,4-diene has been carried out.All of them undergo the aza-di-?-methane rearrangement and yield a cyclopropylimine.The influence of substituents on the 1-aryl group has given support for the proposal that imines with a low ionization potential are less efficient at undergoing the aza-di-?-methane process than imines with a higher ionization potential.This was demonstrated in a quantitative fashion.The involvement of an electron-transfer process in the reaction is discussed.
View MoreSHANGHAI RC CHEMICALS CO.,LTD.
website:http://www.rcc.net.cn
Contact:+86-21-50322175
Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD
website:http://www.jinjingroup.com
Contact:86-574-13989382828
Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Contact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-5161 3915
Address:Shanghai YangPu
Contact:0792-8228321
Address:10TH Floor No.121 binjiang Road Xunyang District
Doi:10.1016/j.tetlet.2010.06.138
(2010)Doi:10.1007/s00706-010-0337-x
(2010)Doi:10.1002/anie.201001772
(2010)Doi:10.1016/j.ejmech.2010.05.039
(2010)Doi:10.1080/10426500903299919
(2010)Doi:10.1039/c0nj00136h
(2010)
