Journal of the Chemical Society. Chemical communications p. 600 - 602 (1987)
Update date:2022-07-29
Topics:
Crisp, Geoffrey T.
Salem, Geoffrey
Stephens, Frederick S.
Wild, S. Bruce
Reaction of (R*,R*)-<(η-C5H5)<1,2-C6H4(PMePh)2>FePH2Ph>PF6 with iodomethane in the presence of triethylamine at 20 deg C produces a separable 4:1 mixture of <(R*,R*),(R*)>- and <(R*,R*),(S*)>-<(η5-C5H5)<1,2-C6H4(PMePh)2>FePHMePh>PF6; the crystal and molecular structure of the major <(R*,R*),(R*)> diastereoisomer is reported.
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