Tetrahedron p. 3903 - 3916 (1987)
Update date:2022-07-29
Topics:
Minami, Ichiro
Tsuji, Jiro
Treatment of alkyl allyl carbonates with a phosphine-free palladium catalyst in acetonitrile affords ketones or aldehydes in high yields.This new method of oxidation of alcohols via allyl carbonates can be applied to various alcohols except simple primary alcohols.The reaction proceeds under neutral conditions and hence various acid- or base-sensitive functional groups are not affected during the reaction.Ruthenium hydride complex is also an effective catalyst.Direct dehydrogenation of secondary or allylic alcohols was carried out by the reaction with allyl methyl carbonate by the catalysis of the ruthenium complex. 1,4-Diols and 1,5-diols are converted to lactones with excess allyl methyl carbonate.
View MoreTaizhou Crene Biotechnology co.ltd
Contact:86-576-88813233 88205808
Address:Economic Developed Zone of Taizhou Zhejiang China
Zhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Liao Cheng All Win Chemicals Co.,LTD
Contact:86+0635-2991582
Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
PharmaResources(Kaiyuan)CO,.Ltd
Contact:+86-21-50720028
Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Doi:10.1021/jm00403a013
(1988)Doi:10.1016/j.ejmech.2008.05.008
(2009)Doi:10.1002/ejoc.200801061
(2009)Doi:10.1021/jo900198b
(2009)Doi:10.1007/BF01919832
(1976)Doi:10.1016/j.tet.2009.01.098
(2009)
