Tetrahedron Letters p. 8209 - 8212 (1995)
Update date:2022-07-31
Topics:
Carrie
Carrie, Daniel
Carboni
Carboni, Bertrand
Vaultier
Vaultier, Michel
Lithioalkynyltriorganoborates generated from the corresponding propargylic acetals rearrange in the presence of boron trichloride thus opening an efficient and convenient route to a variety of homopropargylic alcohols free of the corresponding allenic isomers. Unexpectedly, the parent derivative leads exclusively to the allenic alcohol.
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