Friedel-crafts cyclialkylations of some epoxides. 2. Stereospecificity, substituent, product, and kinetic studies

DOI: 10.1021/jo00379a021

Source and publish data:

Journal of Organic Chemistry p. 425 - 429 (1987)

Update date:2022-07-29

Topics:

Authors:

Taylor, Stephen K.

Davisson, Mark E.

Hissom Jr., B. Rolf

Brown, Sandra L.

Pristach, Holle A.

Schramm, Scott B.

Harvey, Suzanne M.

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Article abstract of DOI:10.1021/jo00379a021

The relative facility of the cyclialkylation of several arylalkyl epoxides was investigated. Stereochemical studies on the cyclialkylation of cis- and trans-2,3-epoxy-5-phenylpentane establish that the stereospecificity of ring formation is as high as 97%

Full text of DOI:10.1021/jo00379a021

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