Friedel-crafts cyclialkylations of some epoxides. 2. Stereospecificity, substituent, product, and kinetic studies

DOI: 10.1021/jo00379a021

Source and publish data:

Journal of Organic Chemistry p. 425 - 429 (1987)

Update date:2022-07-29

Topics:

Authors:

Taylor, Stephen K.

Davisson, Mark E.

Hissom Jr., B. Rolf

Brown, Sandra L.

Pristach, Holle A.

Schramm, Scott B.

Harvey, Suzanne M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00379a021

The relative facility of the cyclialkylation of several arylalkyl epoxides was investigated. Stereochemical studies on the cyclialkylation of cis- and trans-2,3-epoxy-5-phenylpentane establish that the stereospecificity of ring formation is as high as 97%

Full text of DOI:10.1021/jo00379a021

Products guided by the article

Product name:5-m-Tolyl-pentane-1,2-diol

Cas No:114423-20-0

R&D Labs maybe for 114423-20-0

Taizhou YOJOY Chemical Co., Ltd.

Contact:13857143241

Address:Yangfu Industrial Park, Xianju, Zhejiang, P. R. China
SAGECHEM LIMITED

website:http://www.sagechem.com

Contact:+86-571-86818502

Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Esuccess Material Limited

Contact:852-29282288

Address:HONGKONG
Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com

Relevant to this article

Inductive Effects in Neighboring-Group Participation. Destabilization of Carbocations by CC Double Bonds in Solvolyses of 2,2,5,5-Tetramethylcyclopent-3-en-1-yl Tosylates

Doi:10.1021/jo00250a015
(1988)
Synthesis and characterization of Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes with N-salicydene-o-hydroxymethyleneaniline

Doi:10.1016/S0277-5387(00)80480-5
(1988)
Bioactivity-guided isolation of cytotoxic constituents of Brucea javanica collected in Vietnam

Doi:10.1016/j.bmc.2008.10.076
(2009)
Synthesis of novel bicyclic nucleosides with 3,6-anhydro sugar moiety

Doi:10.1080/15257770802341269
(2008)
The use of cellulose (chromatography paper) as a cheap, versatile and non-covalent support for organic molecules during multi-step synthesis

Doi:10.1039/b208083d
(2002)
Development of column-free alkoxycarbonyl, aryloxycarbonyl, and acyl transfer reagents

Doi:10.3987/COM-08-S(N)95
(2008)

Article Doi