Journal of the Chemical Society. Chemical communications p. 1654 - 1655 (1984)
Update date:2022-07-30
Topics:
Goldstein, Melvin J.
Wenzel, Timothy T.
Reduction of semibullvalene (5) with potassium more closely resembles deprotonation of tetrahydropentalenes by n-butyl-lithium-potassium t-pentoxide than it does the reduction of (5) with lithium; the former processes both provide the cyclo-octatetraenyl dianion (4), plausibly via the intermediate bicyclo<3.3.0>octadienediyl dianion (3).
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