The Reductive Decyclizations of Semibullvalene

DOI: 10.1039/c39840001654

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1654 - 1655 (1984)

Update date:2022-07-30

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Authors:

Goldstein, Melvin J.

Wenzel, Timothy T.

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Article abstract of DOI:10.1039/c39840001654

Reduction of semibullvalene (5) with potassium more closely resembles deprotonation of tetrahydropentalenes by n-butyl-lithium-potassium t-pentoxide than it does the reduction of (5) with lithium; the former processes both provide the cyclo-octatetraenyl dianion (4), plausibly via the intermediate bicyclo<3.3.0>octadienediyl dianion (3).

Full text of DOI:10.1039/c39840001654

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