HIGHLY STEREOSELECTIVE REDUCTION OF CHIRAL α-KETO-β,γ-UNSATURATED ACETALS: SYNTHESIS OF BOTH EPIMERIC ALLYL ALCOHOLS BY PROPER CHOICE OF ADDITIVE

DOI: 10.1016/S0040-4039(00)96812-6

Source and publish data:

Tetrahedron Letters p. 5681 - 5682 (1987)

Update date:2022-08-05

Topics:

Authors:

Tamura, Yasumitsu

Annoura, Hirokazu

Fujioka, Hiromichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96812-6

Highly stereoselective reduction of chiral α-keto-β,γ-unsaturated acetals (1a-3a) into each two epimeric optically active allyl alcohols (1b-3b and 1c-3c) was attained by LiAlH4 using additive (LiBr, MgBr2).

Full text of DOI:10.1016/S0040-4039(00)96812-6

Products guided by the article

Product name:(3aR,7aR)-3a-Phenyl-hexahydro-benzofuran-2,6-dione

Cas No:115362-27-1

R&D Labs maybe for 115362-27-1

Shanghai WinTide BioTechnology Co.,Ltd

Contact:86-21-37100630

Address:No. 908 Yunhe Road, Fengxian district, Shanghai
Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,
Dragon Chemical Co., Ltd.

Contact:0571-

Address:zhejing
Accendatech Co., LTD

Contact:+86-22-83718541

Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town

Relevant to this article

Highly chemoselective synthesis of 6-Alkoxy-l-aIkyl(aryl)-3- trifluoroaeetyl-1,4,5,6 tetrahydropyridlines and 1-Alkyl(aryl)-6-anino-3- trifluoroacetyl-1,4,5,6-tetrahydropyridines

Doi:10.1002/ejoc.200801119
(2009)
Renin inhibitors containing hydrophilic groups. Tetrapeptides with enhanced aqueous solubility and nanomolar potency

Doi:10.1021/jm00118a009
(1988)
Ligand differentiated complementary Rh-catalyst systems for the enantioselective desymmetrization of meso-cyclic anhydrides

Doi:10.1016/j.tet.2008.10.075
(2009)
Doi:10.1016/S0020-1693(00)83905-5
(1988)
Synthesis of novel α-amino-acids and derivatives using radical chemistry: Synthesis of L- and D-α-amino-apidic acids, L-α-aminopimelic acid and appropriate unsaturated derivatives

Doi:10.1016/S0040-4020(01)90305-9
(1987)
Antibacterial activity of indolyl-quinolinium derivatives and study their mode of action

Doi:10.1016/j.bmc.2019.02.024
(2019)

Article Doi