HIGHLY STEREOSELECTIVE REDUCTION OF CHIRAL α-KETO-β,γ-UNSATURATED ACETALS: SYNTHESIS OF BOTH EPIMERIC ALLYL ALCOHOLS BY PROPER CHOICE OF ADDITIVE

DOI: 10.1016/S0040-4039(00)96812-6

Source and publish data:

Tetrahedron Letters p. 5681 - 5682 (1987)

Update date:2022-08-05

Topics:

Authors:

Tamura, Yasumitsu

Annoura, Hirokazu

Fujioka, Hiromichi

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Article abstract of DOI:10.1016/S0040-4039(00)96812-6

Highly stereoselective reduction of chiral α-keto-β,γ-unsaturated acetals (1a-3a) into each two epimeric optically active allyl alcohols (1b-3b and 1c-3c) was attained by LiAlH4 using additive (LiBr, MgBr2).

Full text of DOI:10.1016/S0040-4039(00)96812-6

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