RHODIUM CARBENOID MEDIATED CYCLISATIONS. USE OF ETHYL LITHIODIAZOACETATE IN THE PREPARATION OF ω-HYDROXY-, -MERCAPTO-, AND -Boc-AMINO-α-DIAZO-β-KETO ESTERS

DOI: 10.1016/S0040-4039(00)96727-3

Source and publish data:

Tetrahedron Letters p. 5351 - 5352 (1987)

Update date:2022-08-04

Topics:

Authors:

Moody, Christopher J.

Taylor, Roger J.

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Article abstract of DOI:10.1016/S0040-4039(00)96727-3

Reaction of ethyl lithiodiazoacetate with lactones, thiolactones, and lactams (1, 4, 8) gives the diazo-compounds (2, 5, 9), substrates for rhodium carbenoid cyclisation reactions.

Full text of DOI:10.1016/S0040-4039(00)96727-3

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