RHODIUM CARBENOID MEDIATED CYCLISATIONS. USE OF ETHYL LITHIODIAZOACETATE IN THE PREPARATION OF ω-HYDROXY-, -MERCAPTO-, AND -Boc-AMINO-α-DIAZO-β-KETO ESTERS

DOI: 10.1016/S0040-4039(00)96727-3

Source and publish data:

Tetrahedron Letters p. 5351 - 5352 (1987)

Update date:2022-08-04

Topics:

Authors:

Moody, Christopher J.

Taylor, Roger J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96727-3

Reaction of ethyl lithiodiazoacetate with lactones, thiolactones, and lactams (1, 4, 8) gives the diazo-compounds (2, 5, 9), substrates for rhodium carbenoid cyclisation reactions.

Full text of DOI:10.1016/S0040-4039(00)96727-3

Products guided by the article

Product name:ethyl 2-diazo-6-(2-hydroxyphenyl)-3-oxohexanoate

Cas No:115399-70-7

R&D Labs maybe for 115399-70-7

taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany

Relevant to this article

Synthesis and Structure of a Semi-rigid Dinucleating Macrocycle containing the 2,6-Bis(thiomethyl)pyridine Unit and Reactions of its Copper(II) Complex

Doi:10.1039/c39880000579
(1988)
A Trimer of ultrafast nanomotors: synthesis, photochemistry and self-assembly on graphite

Doi:10.1002/chem.200802718
(2009)
A convergent route for the total synthesis of malyngamides O, P, Q, and R

Doi:10.1021/jo9003103
(2009)
Doi:10.1021/ja01549a090
(1958)
Lower rim calix(4)arene ketone derivatives and their interaction with alkali metal cations. Structural and thermodynamic (solution and complexation) characterisation of the tetraphenyl ketone derivative and its sodium complex

Doi:10.1039/b104355m
(2001)
Preparation and characterization of macrocyclic dinickel complexes coligated by tetrazolate ligands

Doi:10.1515/znb-2008-0503
(2008)

Article Doi