RHODIUM CARBENOID MEDIATED CYCLISATIONS. USE OF ETHYL LITHIODIAZOACETATE IN THE PREPARATION OF ω-HYDROXY-, -MERCAPTO-, AND -Boc-AMINO-α-DIAZO-β-KETO ESTERS

DOI: 10.1016/S0040-4039(00)96727-3

Source and publish data:

Tetrahedron Letters p. 5351 - 5352 (1987)

Update date:2022-08-04

Topics:

Authors:

Moody, Christopher J.

Taylor, Roger J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96727-3

Reaction of ethyl lithiodiazoacetate with lactones, thiolactones, and lactams (1, 4, 8) gives the diazo-compounds (2, 5, 9), substrates for rhodium carbenoid cyclisation reactions.

Full text of DOI:10.1016/S0040-4039(00)96727-3

Products guided by the article

Product name:ethyl 2-diazo-6-(2-hydroxyphenyl)-3-oxohexanoate

Cas No:115399-70-7

R&D Labs maybe for 115399-70-7

Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China
Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Allright GC (Jinan) Biotechnology Ltd.

website:https://www.argcbiotech.com/

Contact:86-18405413579-

Address: No.27566 of Jingshiroad, Huaiyin District, Jinan City(250011), Shandong Province, China.

Relevant to this article

Synthesis and Structure of a Semi-rigid Dinucleating Macrocycle containing the 2,6-Bis(thiomethyl)pyridine Unit and Reactions of its Copper(II) Complex

Doi:10.1039/c39880000579
(1988)
A Trimer of ultrafast nanomotors: synthesis, photochemistry and self-assembly on graphite

Doi:10.1002/chem.200802718
(2009)
A convergent route for the total synthesis of malyngamides O, P, Q, and R

Doi:10.1021/jo9003103
(2009)
Doi:10.1021/ja01549a090
(1958)
Lower rim calix(4)arene ketone derivatives and their interaction with alkali metal cations. Structural and thermodynamic (solution and complexation) characterisation of the tetraphenyl ketone derivative and its sodium complex

Doi:10.1039/b104355m
(2001)
Preparation and characterization of macrocyclic dinickel complexes coligated by tetrazolate ligands

Doi:10.1515/znb-2008-0503
(2008)

Article Doi