Isometallocenes. Part 1. Polymethylated Isocobaltocenium Salts; a General Route to (1+)

DOI: 10.1039/DT9870002757

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2757 - 2760 (1987)

Update date:2022-08-04

Topics:

Authors:

Cook, Malcolm R.

Harter, Peter

Pauson, Peter L.

Sraga, Jan

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Article abstract of DOI:10.1039/DT9870002757

The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes <2> and are described.Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations (1+) of which seven new examples are described. some carbonyl substitutions of the cation (1+) are also reported.

Full text of DOI:10.1039/DT9870002757

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