Tetrahedron Letters p. 5555 - 5558 (1987)
Update date:2022-08-02
Topics:
Randles, K. R.
Storr, R. C.
Flash vacuum pyrolysis of N-(2-methylphenyl)benzimidoyl chlorides and N,N-dimethyl-N'-(2-methylphenyl)formamidines provides a simple route to 2-aryl- and 2-unsubstituted indoles.Pyrolysis of N,N-dimethyl-N-(2-methylphenyl)-acetamidines gives mainly quinolines in a reaction which reveals a novel, high temperature rearrangement of 3,4-dihydroquinolines.
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