METHOXY(PHENYLTHIO)METHANE AS AN AMBI-EQUVIVALENT OF A METHOXY- OR PHENYLTHIOMETHYLENE 1,1-DIPOLE

DOI: 10.1016/S0040-4039(01)91357-7

Source and publish data:

Tetrahedron Letters p. 6299 - 6302 (1987)

Update date:2022-08-03

Topics:

Authors:

Sato, Tsuneo

Okura, Shuji

Otera, Junzo

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4039(01)91357-7

Methoxy(phenylthio)methane undergoes electrophilic alkylation followed by nucleophilic allylation or propargylation which is dramatically changed depending on the Lewis acid employed providing a methoxy- or phenylthiomethylene 1,1-dipole synthon.

Full text of DOI:10.1016/S0040-4039(01)91357-7

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