PRENYLATION OF CAMPHENE - A CARBOCATIONIC ROUTE TO ISOSANTALENE AND ITS DERIVATIVES

DOI: 10.1016/S0040-4020(01)83451-7

Source and publish data:

Tetrahedron p. 4119 - 4124 (1987)

Update date:2022-07-31

Topics:

Authors:

Rahman, Azizur

Baeuml, Englbert

Klein, Herbert

Mayr, Herbert

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Article abstract of DOI:10.1016/S0040-4020(01)83451-7

Camphene 1 is converted into 8-chloromethylcamphene 3 via Prins reaction.Treatment of 3 with zinc chloride/ether in the presence of isobutene gives the 1:1 adduct 11, from which isosantalene 7, its isomer 6, and the corresponding alcohol 5 are obtained.

Full text of DOI:10.1016/S0040-4020(01)83451-7

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