An Anomalous Dipyrrole Product from Attempted Synthesis of a Tetraarylporphyrin

DOI: 10.1021/jo00260a009

Source and publish data:

Journal of Organic Chemistry p. 5847 - 5849 (1988)

Update date:2022-08-05

Topics:

Authors:

Cavaleiro, Jose A. S.

Condesso, M. de Fatima P. N.

Olmstead, Marilyn M.

Oram, Douglas E.

Snow, Kevin E.

Smith, Kevin M.

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Article abstract of DOI:10.1021/jo00260a009

Heating of o-acetoxybenzaldehyde with pyrrole in hot acetic acid under Adler/Rothemund conditions yields a bright red (γ_max 515 nm) dipyrrolic compound and only minor quantities of the expected tetraarylporphyrin.Using NMR, mass spectrometry, a

Full text of DOI:10.1021/jo00260a009

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