Dyotropic Rearrangement of Cycloalkyl β-Lactones. Formation of Spiro vs Fused Butyrolactones as a Function of Ring Size

DOI: 10.1021/jo00260a021

Source and publish data:

Journal of Organic Chemistry p. 5922 - 5927 (1988)

Update date:2022-09-26

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Authors:

Black, Howard T.

DuBay, William J.

Tully, Paul S.

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Article abstract of DOI:10.1021/jo00260a021

Trans 3-substituted-4-cycloalkyl β-lactones 4 and 8 have been prepared via the condensation of appropriately substituted acetic acid dianions 1 with cyclohexane- or cyclopentanecarboxaldehyde to afford the corresponding diastereomerically pure β-hydroxy a

Full text of DOI:10.1021/jo00260a021

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