SYNTHESIS OF (+/-)-14-EPIUPIAL BY MANGANESE(III) γ-LACTONE ANNULATION

DOI: 10.1016/S0040-4020(01)87738-3

Source and publish data:

Tetrahedron p. 5567 - 5582 (1987)

Update date:2022-08-02

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Authors:

Paquette, Leo A.

Schaefer, Anthony G.

Springer, James P.

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Article abstract of DOI:10.1016/S0040-4020(01)87738-3

The total synthesis of racemic 14-epiupial (3) is described.The preparation of 3 is achieved in 23 steps starting from 8.In the key step, manganese(III) acetate acts on the monocarboxylic acid derived from 17b to promote concurrent formation of the bicycl

Full text of DOI:10.1016/S0040-4020(01)87738-3

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