SYNTHESIS OF (+/-)-14-EPIUPIAL BY MANGANESE(III) γ-LACTONE ANNULATION

DOI: 10.1016/S0040-4020(01)87738-3

Source and publish data:

Tetrahedron p. 5567 - 5582 (1987)

Update date:2022-08-02

Topics:

Authors:

Paquette, Leo A.

Schaefer, Anthony G.

Springer, James P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)87738-3

The total synthesis of racemic 14-epiupial (3) is described.The preparation of 3 is achieved in 23 steps starting from 8.In the key step, manganese(III) acetate acts on the monocarboxylic acid derived from 17b to promote concurrent formation of the bicycl

Full text of DOI:10.1016/S0040-4020(01)87738-3

Products guided by the article

Product name:(1S,5S,6R,8S)-8-Iodo-9-methoxymethoxy-5,6-dimethyl-bicyclo[3.3.1]nonane-2,2-dicarboxylic acid dimethyl ester

Cas No:117211-58-2

R&D Labs maybe for 117211-58-2

Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China

Relevant to this article

Ultrafast Electron Transfer in Optically Prepared "Simple" Ion Pairs: The Mechanism at High Donor Concentration

Doi:10.1021/j100007a036
(1995)
2-Substituted 5,6-dimethyl-3-phenylsulfonyl-pyrazolo[1,5-a]pyrimidines: New series of highly potent and specific serotonin 5-HT₆ receptor antagonists

Doi:10.1016/j.ejmech.2011.01.038
(2011)
Stereoselective routes for the total synthesis of (+)-cryptocarya diacetate

Doi:10.1002/hlca.200800355
(2009)
5-Methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines in the reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes

Doi:10.1016/j.mencom.2008.11.003
(2008)
Discovery of the first series of small molecule H5N1 entry inhibitors

Doi:10.1021/jm900275m
(2009)
New 2,2'-Bipyridine Derivatives and Their Luminescence Properties with Europium(III) and Terbium(III) Ions

Doi:10.1002/hlca.19920750512
(1992)

Article Doi