Tetrahedron p. 5567 - 5582 (1987)
Update date:2022-08-02
Topics:
Paquette, Leo A.
Schaefer, Anthony G.
Springer, James P.
The total synthesis of racemic 14-epiupial (3) is described.The preparation of 3 is achieved in 23 steps starting from 8.In the key step, manganese(III) acetate acts on the monocarboxylic acid derived from 17b to promote concurrent formation of the bicycl
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