General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper

DOI: 10.1021/jo00259a038

Source and publish data:

Journal of Organic Chemistry p. 5789 - 5791 (1988)

Update date:2022-08-05

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Authors:

Berk, Scott C.

Knochel, Paul

Yeh, Ming Chang P.

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Article abstract of DOI:10.1021/jo00259a038

A general synthesis of highly functionalized benzylic zinc organometallics is described.The corresponding copper derivatives, formed by a transmetalation with CuCN*2LiCl, react in high yields with allylic halides, enones, acyl chlorides, and aldehydes.

Full text of DOI:10.1021/jo00259a038

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