Tetrahedron Letters p. 2251 - 2254 (1988)
Update date:2022-08-04
Topics:
Bartoli, Giuseppe
Marcantoni, Enrico
Bosco, Marcella
Dalpozzo, Renato
In contrast to alkyl Grinard reagents, the allyl reagent reacts with nitroarenes via 1,2 addition to the nitro group.The "in situ" treatment of the unstable intermediate adduct with LiAlH4 in the presence of catalytic Pd/C provides a general synthesis of N-allyl-N-arylhydroxylamines or N-allylanilines.
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