Journal of Organic Chemistry p. 317 - 327 (1989)
Update date:2022-07-29
Topics: Reactions α-Alkylation Regioselective Substituent Silicon
Horvath, Raymond F.
Chan, Tak Hang
α-Silylallyl carbanions having metal-ion complexing substituents on silicon react with alkyl halides to give α-substituted allylsilanes regioselectively.The extent of α-selection depends significantly on the nature of the ligand and solvent.The synthetic utility of these systems is demonstrated by application in the synthesis of α-(E)-bisabolene.
View MoreContact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Ji'an Hairui Natural Plant Co. Ltd.
Contact:0796-8105528
Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.
Contact:+86-512-6585 6968
Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
Contact:86 311 85902108 / 85902109
Address:room 1001-1005 ,huanghe Road ,shijiazhuang ,China
SHANGHAI RC CHEMICALS CO.,LTD.
website:http://www.rcc.net.cn
Contact:+86-21-50322175
Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Doi:10.1055/s-1988-27505
(1988)Doi:10.1021/ja904506u
(2009)Doi:10.1021/acs.joc.1c00704
(2021)Doi:10.1039/c39880001137
(1988)Doi:10.1016/j.tet.2009.07.018
(2009)Doi:10.1002/chem.200900744
(2009)
