Journal of Organic Chemistry p. 317 - 327 (1989)
Update date:2022-07-29
Topics: Reactions α-Alkylation Regioselective Substituent Silicon
Horvath, Raymond F.
Chan, Tak Hang
α-Silylallyl carbanions having metal-ion complexing substituents on silicon react with alkyl halides to give α-substituted allylsilanes regioselectively.The extent of α-selection depends significantly on the nature of the ligand and solvent.The synthetic utility of these systems is demonstrated by application in the synthesis of α-(E)-bisabolene.
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