Dirhodium(II) Tetra(triphenylacetate): A Highly Efficient Catalyst for the Site-selective Intramolecular C-H Insertion Reactions of α-Diazo β-Keto Esters

DOI: 10.1016/S0040-4039(00)79063-0

Source and publish data:

Tetrahedron Letters p. 2709 - 2712 (1992)

Update date:2022-08-02

Topics:

Authors:

Hashimoto, Shun-ichi

Watanabe, Nobuhide

Ikegami, Shiro

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Article abstract of DOI:10.1016/S0040-4039(00)79063-0

Dirhodium(II) tetra(triphenylacetate), Rh2(TPA)4, featured by a bulky bridging ligand has been demonstrated to exhibit an exceptionally high order of selectivity for C-H insertion into methylene over methine in catalytic decompositions of α-diazo β-keto e

Full text of DOI:10.1016/S0040-4039(00)79063-0

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