REGIO- AND STEREOSELECTIVE PREPARATION OF SILYL ENOL ETHERS BY ALKYLIDENATION OF SILYL ESTERS

DOI: 10.1016/0040-4039(88)85336-X

Source and publish data:

Tetrahedron Letters p. 1065 - 1068 (1988)

Update date:2022-08-03

Topics: Silyl enol ethers Stereoselective Regioselective Alkylidenation

Authors:

Takai, Kazuhiko

Kataoka, Yasutaka

Okazoe, Takashi

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/0040-4039(88)85336-X

Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.

Full text of DOI:10.1016/0040-4039(88)85336-X

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