Tetrahedron Letters p. 1065 - 1068 (1988)
Update date:2022-08-03
Topics: Silyl enol ethers Stereoselective Regioselective Alkylidenation
Takai, Kazuhiko
Kataoka, Yasutaka
Okazoe, Takashi
Utimoto, Kiitiro
Treatment of trimethylsilyl esters with a reagent for alkylidenation of carbonyl groups derived from 1,1-dibromoalkane, zinc, TiCl4, and TMEDA in THF gives Z-trimethylsilyl enol ethers in a regio- and stereoselective manner.
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(1943)
